Carbon fibers, each far thinner than a human hair, are truly wonders of technology. Due to their strength, durability and unique thermal properties, they are highly promising for use in a wide variety of industrial fields.
      With its extensive experience of carbon chemistry, Mitsubishi Chemical has established itself as a leading global manufacturer of carbon fibers. Mr. Akira Nakagoshi, who managed the Carbon Fiber Technical Group at Mitsubishi Chemical Functional Products, Inc. prior to the company’s integration into Mitsubishi Plastics in April 2008, talks to the Monitor about these achievements.

Akira Nakagoshi, Senior Manager,
Carbon Fiber Department,
Carbon Fiber Technical Group,
Industrial Materials Division

Please give an overview of your company’s experience of carbon fiber development.
Carbon fiber was an innovative technology for Mitsubishi Chemical Functional Products, and is now also an area of innovation for Mitsubishi Plastics following the integration this spring. The achievements in this area reflect seven decades of carbon chemistry experience. Our carbon fiber business began with the development of derivatives from coal tar produced during the manufacture of coke.
      A strand of carbon fiber is a collection of black fibers 10 times thinner than human hairs. PAN-based carbon fibers are made from synthetic acrylic fibers, and pitch-based carbon fibers from petroleum or coal. Japanese companies now have a 70% share of the world markets for both types. Our DIALEAD® range of products were the first carbon fibers in the world to be developed from coal tar pitch. Compared with PAN-based carbon fibers, which are used in aircraft parts and other applications that require material strength at a standard degree of stiffness, DIALEAD® carbon fibers offer other advantages, including not only a high degree of stiffness but also thermal conductivity and zero thermal expansion. The last property, which means that the material does not at all expand as temperatures increase, is particularly valuable.
  What challenges did Mitsubishi Chemical Functional Products face
during the development and introduction of DIALEAD®?
Commercial production of DIALEAD® started in 1987, but it was not until the mid-1990s that it began to be used in industrial applications, for instance rollers and beams. DIALEAD® printing rollers have gained an excellent reputation because of their rigidity, which allows them to rotate at a very high speed, and because of their lightness, which makes them easier to maintain. They are also highly regarded as high-performance film rollers capable of preventing wrinkling.
      Mitsubishi Chemical Functional Products came close to abandoning this business segment. However, between 1993 and 1995, we found a new path to success in the European market. Europe is a major center for aircraft manufacturing, and there are many companies involved in the molding and processing of composite materials. We spent 140—150 days each year explaining the properties of carbon fiber. A key characteristic of pitch-based carbon fiber is its ability to resist excessive flexing. The first company to take advantage of this was a manufacturer of fishing rods. A French satellite manufacturer was delighted to find that our carbon fiber had a zero thermal expansion ratio. We learned that our products could be used in ways that we had never imagined.
  What are some of the uses for DIALEAD® today?
As pitch-based carbon fiber does not expand as temperatures increase, it was used in the construction of the ALMA radio telescope facility in the Chilean highlands. At this high-precision facility, researchers study the universe by combining the signals received by an array of 80 antennae, a process called interferometry.
      However, if even one antenna was out of alignment due to temperature variations, this array could not produce images. After studying the thermal expansion properties of various materials, the designers eventually selected our carbon fibers.
      Pitch-based carbon fibers also have excellent vibration-damping properties and are ideal for vibration-sensitive products, such as components for industrial robots in LCD TV factories. The hands of the robots used to carry glass substrates must be able to fully damp vibrations quickly. Here, DIALEAD® is helping to reduce processing times.
      DIALEAD® is also used as a reinforcing material in the construction industry. When applied to just 8% of a cross-sectional area, strength is doubled. It was used on the London Underground to strengthen over 400 cast-iron pillars, which had cracked due to rusting during the 120 years since their construction.
What is the future for carbon fiber?
This is an area of huge potential. Carbon fiber is expected to play a leading role in the reduction of greenhouse gases, as it improves energy efficiency by reducing the weight of vehicles and other machinery. Also, because it can be used to strengthen existing structures, it reduces the need for new resources.
      Carbon fiber is also playing a role in Europe’s expanding wind power generation industry as the material for wind turbine blades. Some of the larger turbines have rotor diameters exceeding 100 meters. The world’s largest, currently under construction in Germany, has a rotor diameter of 127 meters and will be able to generate over 6 MW of electricity. When generating capacities reach the 10 MW level, blade diameters will need to reach some 180 meters, and it will be necessary to find solutions for the problems of vibration and distortion. Over the next 10 years, I believe we will see many carbon fiber products contributing to the solution of environmental problems.
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